Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes
Sign Up to like & getrecommendations! Published in 2018 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-018-2321-2
Abstract: A new method for the synthesis of complexes PtIV(NHC)X4L (NHC is N-heterocyclic carbene of imidazole or benzimidazole series; X = Cl, Br; L is N-coordinated pyridine or NHC) based on mechanochemical oxidation of complexes PtII(NHC)X2L… read more here.
Keywords: platinum complexes; heterocyclic carbenes; mechanochemical synthesis; complexes heterocyclic ... See more keywords
Piano stool complexes of N-heterocyclic carbene ligands bearing a galactose-derived substituent
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119651
Abstract: Abstract Piano stool complexes of NHC ligands bearing a chiral auxiliary derived from α-ᴅ-galactose, and linked through the C-6 carbon atom, have been synthesized and structurally characterized by single crystal X-ray diffraction. [(η6-C6H3Me3)RuCl2(κC-1,3-MeNC3H2NR)], R = 1,2:3,4-di-O-isopropylidene-6-deoxy-α-D-galactopyran-6-yl, (4)… read more here.
Keywords: piano stool; complexes heterocyclic; ligands bearing; stool complexes ... See more keywords
Synthesis and Photophysical Characterization of Cyclometalated Ruthenium Complexes with N-Heterocyclic Carbene Ligands
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00354
Abstract: In the search of new ligand environment for the ruthenium(II) complexes with pyridine-type ligands, we developed seven new cyclometalated ruthenium complexes with N-heterocyclic carbenes (NHCs). In a two-step procedure, we synthesized complexes with the general… read more here.
Keywords: ruthenium; photophysical characterization; synthesis photophysical; complexes heterocyclic ... See more keywords
Vanadium complexes with N-heterocyclic vinylidene ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00768a
Abstract: The preparation and the structural characterization of vanadium complexes with terminal and bridging N-heterocyclic vinylidene ligands is reported. The synthesis of the complexes was enabled by utilization of diazoolefins as ligand precursors. Structural data and… read more here.
Keywords: complexes heterocyclic; heterocyclic vinylidene; vinylidene ligands; vanadium complexes ... See more keywords
Homoleptic Complexes of Heterocyclic Curcuminoids with Mg(II) and Cu(II): First Conformationally Heteroleptic Case, Crystal Structures, and Biological Properties
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031434
Abstract: We report herein the synthesis and characterization of three heterocyclic curcuminoid ligands and their homoleptic metal complexes with magnesium and copper. Thus, N-methyl-2-pyrrolecarboxaldehyde, Furan-2-carboxaldehyde, and 2-Thiophenecarboxaldehyde were condensed with 2,4-pentanedione-boron trioxide complex. The first N-methyl-2-pyrrole… read more here.
Keywords: metal complexes; complexes heterocyclic; case; conformationally heteroleptic ... See more keywords