New dialkylenetriamine zinc complexes as highly efficient ROP catalysts
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DOI: 10.1016/j.mencom.2020.09.014
Abstract: The reaction of Zn[N(SiMe3)2]2 with N-alkyl-N-[ω- (pentafluorophenylamino)alkyl]-N-[2-(pentafluorophenylamino) ethyl]amines afforded new bicyclic zinc complexes. The complexes initiate ring-opening polymerization of ɛ-caprolactone and trimethylene carbonate to give the corresponding polymers with high molecular weight and satisfactory degree… read more here.
Keywords: zinc; new dialkylenetriamine; complexes highly; dialkylenetriamine zinc ... See more keywords