Synthesis of Molybdenum Imido 2-Adamantylidene Complexes through α Hydrogen Abstraction
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DOI: 10.1021/acs.organomet.0c00244
Abstract: Addition of 2-adamantylMgBr in diethyl ether to Mo(NAr)2(Cl)2(DME) (Ar = 2,6-i-Pr2C6H3) gave Mo(NAr)2(2-Ad)2 (2-Ad = 2-adamantyl, DME = 1,2-dimethoxyethane), from which Mo(NAr)(Adene)(OTf)2(DME) (1... read more here.
Keywords: complexes hydrogen; imido adamantylidene; adamantylidene complexes; synthesis molybdenum ... See more keywords