Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons
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DOI: 10.1021/acs.organomet.7b00385
Abstract: The tris(pentamethylcyclopentadienyl) complexes, (C5Me5)3Ln (Ln = Tb, Dy, Ho, and Er), have been synthesized to determine if structural trends observed with the larger rare-earth metals, La–Gd, extend to the smaller metals and to determine the… read more here.
Keywords: tris pentamethylcyclopentadienyl; lanthanides solution; late lanthanides; c5me5 ... See more keywords
1,3-N,O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles.
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DOI: 10.1039/c6cs00715e
Abstract: 1,3-N,O-Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral amino acids in metalloproteins. These structural units also display diverse coordination modes, which lend themselves to applications in catalysis as well as novel… read more here.
Keywords: late transition; transition; metals ligands; transition metals ... See more keywords