Concerted Electron Transfer in Iminopyridine Chromium Complexes: Ligand Effects on the Polymerization of Various (Di)olefins
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DOI: 10.1021/acs.organomet.8b00812
Abstract: A study of reactions among CrCl2, CrCl3(THF)3, and iminopyridine ligands differing in the nature of the substituents at the iminic carbon and at the ortho positions of the aryl ring (2,6-R12C6H3N═C... read more here.
Keywords: complexes ligand; concerted electron; chromium complexes; electron transfer ... See more keywords
Nickel(ii) complexes of a 3N ligand as a model for diketone cleaving unusual nickel(ii)-dioxygenase enzymes.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04739h
Abstract: Diketone substrate bound nickel(ii) complexes of 2,6-bis(1-methylbenzimidazolyl)pyridine have been synthesized and characterized as relevant active site models for unusual diketone cleaving Ni(ii)-dependent enzymes Ni-ARD and DKDO. The average Ni-Npy/benzim bond distances (2.050-2.107 Å) of model… read more here.
Keywords: complexes ligand; diketone; ligand model; nickel complexes ... See more keywords