Complexes between neutral oxyacid beryllium salts and dihydrogen: a possible way for hydrogen storage?
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01679h
Abstract: Accurate ab initio calculations reveal that oxyacid beryllium salts yield rather stable complexes with dihydrogen. The binding energies range between -40 and -60 kJ mol-1 for 1 : 1 complexes, remarkably larger than others previously reported for… read more here.
Keywords: neutral oxyacid; complexes neutral; salts dihydrogen; oxyacid beryllium ... See more keywords
Unravelling a general mechanism of converting ionic B/N complexes into neutral B/N analogues of alkanes: Hδ+Hδ- dihydrogen bonding assisted dehydrogenation.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc07133d
Abstract: Long-sought mechanisms for the conversion of diammoniate of diborane ([NH3BH2NH3]+[BH4]-) into NH3BH3 and [NH2BH2]n as well as ammonium aminodiborane ([NH4]+[BH3NH2BH3]-) into a butane analogue, NH3BH2NH2BH3, have been elucidated on the basis of extensive experimental and… read more here.
Keywords: converting ionic; mechanism converting; complexes neutral; general mechanism ... See more keywords
Structural Diversity of Cationic Copper(II) Complexes with Neutral Nitrogen-Containing Organic Ligands in Compounds with Boron Cluster Anions and Their Derivatives (Review)
Sign Up to like & getrecommendations! Published in 2020 at "Russian Journal of Inorganic Chemistry"
DOI: 10.1134/s0036023620040026
Abstract: Abstract Data on the known-to-date copper(II) complexes with neutral nitrogen-containing ligands (2,2'-bipyridyl, 1,10-phenanthroline, 2,2'-bipyridylamine, aminoguanidine, ammonia, pyridine derivatives, etc.) with boron cluster anions, including those containing bridging OH – and $${\text{CO}}_{3}^{{2 - }}$$ groups, are… read more here.
Keywords: copper; copper complexes; complexes neutral; cluster anions ... See more keywords