Platinum complexes from pyridine-imine ligands with pendent functional groups
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2021.120387
Abstract: Abstract Notable differences are observed in reactions of platinum(II) precursor complexes with pyridine-imine ligands of formula 2-C5H4NCH=NCH2-C6H4OR with R = Me or H. The ligand 2-C5H4NCH=N-2-C6H4OMe, L1, gave simple complexes [PtXY(L1)], XY = Me,Me; Me,Cl;… read more here.
Keywords: imine ligands; ligand c5h4nch; c5h4nch nch2; platinum ... See more keywords
Pd(II) Complexes with Pyridine Ligands: Substituent Effects on the NMR Data, Crystal Structures, and Catalytic Activity
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01996
Abstract: A wide range of functionalized pyridine ligands have been employed to synthesize a variety of Pd(II) complexes of the general formulas [PdL4](NO3)2 and [PdL2Y2], where L = 4-X-py and Y = Cl– or NO3–. Their… read more here.
Keywords: ligands substituent; effects nmr; chemistry; complexes pyridine ... See more keywords
Zn and Ni complexes of pyridine-2,6-dicarboxylates: crystal field stabilization matters!
Sign Up to like & getrecommendations! Published in 2019 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989019007461
Abstract: Different electron configurations for ZnII (d 10) and NiII (d 8) lead to less regular coordination environments for the former: ZnII adopts strongly distorted octahedral or even fivefold coordination spheres whereas NiII favours rather regular… read more here.
Keywords: pyridine dicarboxylates; crystal field; stabilization matters; field stabilization ... See more keywords