XPS detection of unusual Cu(II) to Cu(I) transition on the surface of complexes with redox-active ligands
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Electron Spectroscopy and Related Phenomena"
DOI: 10.1016/j.elspec.2019.06.010
Abstract: Abstract Electronic structure of copper complexes with redox-active ligands was studied by XPS. The temperature dependence of the redistribution of electron and spin densities was shown. A low temperature anomaly of magnetic properties of the… read more here.
Keywords: complexes redox; copper complex; active ligands; xps detection ... See more keywords
Solvent-Induced Redox Isomerism of Cobalt Complexes with Redox-Active Bisguanidine Ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03983
Abstract: Redox-isomeric coordination compounds, in which the magnetic and optical properties could be varied by a stimulated intramolecular electron transfer between the metal and a redox-active ligand, are of interest for several applications in catalysis and… read more here.
Keywords: active bisguanidine; redox active; chemistry; cobalt complexes ... See more keywords
Nickel(II) Complexes with Redox Noninnocent Octaazamacrocycles as Catalysts in Oxidation Reactions.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01700
Abstract: Nickel(II) complexes with 15-membered (1-5) and 14-membered (6) octaazamacrocyclic ligands derived from 1,2- and 1,3-diketones and S-methylisothiocarbohydrazide were prepared by template synthesis. The compounds were characterized by elemental analysis, electrospray ionization mass spectrometry, IR, UV-vis,… read more here.
Keywords: octaazamacrocycles catalysts; noninnocent octaazamacrocycles; catalysts oxidation; complexes redox ... See more keywords
Reactivity of Aluminum Complexes of Redox-Active Ligand toward N-Heterocyclic Carbene and Its Thione
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00611
Abstract: The reaction of dialane (dpp-Bian)Al–Al(dpp-Bian) (1) (dpp-Bian is dianion of 1,2-bis[(2,6-diisopropylphenyl)imino]-acenaphthene) with 1 mol equiv of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene ... read more here.
Keywords: reactivity aluminum; active ligand; complexes redox; dpp bian ... See more keywords
Cobalt complexes with redox-active anthraquinone-type ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00586a
Abstract: Three anthraquinone-type multidentate ligands, HL1-3 (HL = 2-R-1H-anthra[1,2-d]imidazole-6,11-dione; HL1: R = (2-pyridyl), HL2; R = (4,6-dimethyl-2-pyridyl), HL3; R = (6-methoxy-2-pyridyl)), were prepared, and their complexation behaviour was investigated. Three bis-chelate cobalt complexes with the formula… read more here.
Keywords: complexes redox; anthraquinone type; cobalt; cobalt complexes ... See more keywords
Computational insight into magnetic behavior and properties of the transition metal complexes with redox-active ligands: a DFT approach
Sign Up to like & getrecommendations! Published in 2018 at "Pure and Applied Chemistry"
DOI: 10.1515/pac-2017-0803
Abstract: Abstract Various aspects related to the use of DFT method for the study of magnetic, geometry and energetic properties of transition metal complexes with redox-active ligands are considered. Particular attention is given to the correct… read more here.
Keywords: transition metal; properties transition; complexes redox; metal complexes ... See more keywords
Sn and Ge Complexes with Redox-Active Ligands as Efficient Interfacial Membrane-like Buffer Layers for p-i-n Perovskite Solar Cells
Sign Up to like & getrecommendations! Published in 2023 at "Membranes"
DOI: 10.3390/membranes13040439
Abstract: Inverted perovskite solar cells with a p-i-n configuration have attracted considerable attention from the research community because of their simple design, insignificant hysteresis, improved operational stability, and low-temperature fabrication technology. However, this type of device… read more here.
Keywords: redox active; solar cells; perovskite solar; active ligands ... See more keywords