Aluminium complexes of salanol ligands: coordination chemistry and stereoselective lactide polymerization.
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DOI: 10.1039/d0cc05957a
Abstract: The tetradentate dianionic {ONNO}-type salanol ligands featuring phenolate and alcoholate arms and a chiral-bipyrrolidine core are introduced. The diastereoselectively-formed {ONNO}-Al-OBn complexes catalyze the ring-opening polymerization of rac-lactide and meso-lactide by either the dual stereocontrol or… read more here.
Keywords: polymerization; complexes salanol; aluminium complexes; chemistry ... See more keywords