Electrocatalytic Nitrite Reduction With Polynuclear Copper(I) Complexes Supported By 2‐Mercaptopyridine Ligand
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DOI: 10.1002/cctc.202500374
Abstract: The electrochemical nitrite reduction to ammonia is a growing interest in chemistry as it can be a potential alternative to the energy‐intensive Haber–Bosch. In this work, two copper complexes supported by pyridine‐2‐thiol (PySH), [CuI6(PyS)6] (1),… read more here.
Keywords: copper complexes; complexes supported; copper; electrocatalytic nitrite ... See more keywords
Synthesis, Structure, and Reductive Elimination of Cationic Monoarylpalladium(IV) Complexes Supported by a Tripodal Oxygen Ligand
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700326
Abstract: Cationic monoaryl–PdIV complexes supported by the Klaui tripodal ligand [Co(η5-C5H5){P(O)(OEt)2}3]– (LOEt–) were synthesized, and their reductive elimination was studied. Treatment of trans-[Pd(PPh3)2(Ar)(I)] and [{Pd(η2-ppytBu)Cl}2] [ppytBuH = 2-(4-tert-butylphenyl)pyridine] with [AgLOEt] afforded [Pd(Ar)(PPh3)(η2-LOEt)] [Ar = Ph (1),… read more here.
Keywords: complexes supported; loet; elimination; loet pf6 ... See more keywords
Catalytic oxidation of benzene to phenol with hydrogen peroxide over Fe-terpyridine complexes supported on a cation exchange resin
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DOI: 10.1016/j.catcom.2018.08.011
Abstract: Abstract The catalytic activity of [Fe(terpy)2]2+ complexes supported on the cation exchange resins, ([Fe(terpy)2]2+@resin), was investigated for the oxidation of benzene with H2O2 to yield phenol. The catalytic activity of an [Fe(terpy)2]2+@Nafion catalyst for the… read more here.
Keywords: supported cation; resin; complexes supported; oxidation ... See more keywords
Mononuclear nickel (II) and copper (II) coordination complexes supported by bispicen ligand derivatives: Experimental and computational studies
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DOI: 10.1016/j.ica.2016.09.001
Abstract: Abstract The synthesis, characterization and density functional theory calculations of mononuclear Ni and Cu complexes supported by the N,N′-dimethyl-N,N′-bis-(pyridine-2-ylmethyl)-1,2-diaminoethane ligand and its derivatives are reported. The complexes were characterized by X-ray crystallography as well as… read more here.
Keywords: coordination; complexes supported; geometry; ligand derivatives ... See more keywords
Synthesis, characterization, and reactivity of copper complexes supported by the TPMEN ligand framework
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.09.041
Abstract: Abstract Two new Cu(II) complexes supported by nitrogen-rich ligands have been synthesized and characterized by absorption spectroscopy, magnetic moment, and cyclic voltammetry. Complex 1 is supported by the ligand TPMEN (N,N,N′-tris(2-pyridylmethyl)-N′-methylethylenediamine) with two amine and… read more here.
Keywords: reactivity copper; complexes supported; copper complexes; characterization reactivity ... See more keywords
Monomeric zinc(II) amide complexes supported by bidentate, benzannulated phenanthridine amido ligands
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DOI: 10.1016/j.poly.2019.01.023
Abstract: Abstract The first examples of homoleptic zinc amides (1-Zn and 2-Zn) supported by chelating, benzannulated 4-amidophenanthridine ligands (L1, L2) are reported. The organometallic compounds were characterized fully both in solution (NMR, UV–Vis, electrochemistry, emission spectroscopy)… read more here.
Keywords: zinc amide; monomeric zinc; complexes supported; zinc ... See more keywords
Platinum(II)-Substituted Phenylacetylide Complexes Supported by Acyclic Diaminocarbene Ligands.
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DOI: 10.1021/acs.inorgchem.2c00510
Abstract: We introduce phosphorescent platinum aryl acetylide complexes supported by tert-butyl-isocyanide and strongly σ-donating acyclic diaminocarbene (ADC) ligands. The precursor complexes cis-[Pt(CNtBu)2(C≡CAr)2] (4a-4f) are treated with diethylamine, which undergoes nucleophilic addition with one of the isocyanides… read more here.
Keywords: platinum substituted; complexes supported; acyclic diaminocarbene; substituted phenylacetylide ... See more keywords
C-P Bond Cleavage Through Hydrogenation in Ruthenium Complexes Supported by P,N Ligands.
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DOI: 10.1021/acs.inorgchem.4c04275
Abstract: The reactivity of ruthenium hydride complexes supported by 2-((di-tert-butylphosphaneyl)methyl)pyridine, L1 and 2-(di-tert-butylphosphaneyl)pyridine, L2, was explored. The reaction of {Ru(COD)Cl2}x with L1 in the presence of base and 10 bar of H2 gave the expected complex… read more here.
Keywords: ruthenium; reaction; hydrogenation; complexes supported ... See more keywords
Bis(tetramethylaluminate) Lanthanide Complexes Supported by Bi- and Tridentate Amidinate Ligands: Performance in Isoprene Polymerization
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DOI: 10.1021/acs.organomet.1c00061
Abstract: The isolable bis(tetramethylaluminate) lanthanide complexes [2-R2,6-XC6H4NC(tBu)(2,6-R12C6H3)]Ln(AlMe4)2 (R1 = R2 = X = Me, Ln = La (1); R1 = R2 = X = Me, Ln = Nd (2); R1 = iPr, R2 = H, X… read more here.
Keywords: supported tridentate; complexes supported; lanthanide complexes; bis tetramethylaluminate ... See more keywords
Dimeric Rh Complexes Supported by a Bridging Phosphido/Bis(Phosphine) PPP Ligand
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DOI: 10.1021/acs.organomet.3c00492
Abstract: Rh complexes of a tridentate PPP ligand bearing 1,2-pyrrolediyl linkers have been prepared, including examples with the central P donor being either a phosphine or a phosphide. Three bimetallic Rh complexes containing the diamandoid Rh2P2… read more here.
Keywords: phosphido; ppp ligand; phosphine; dimeric complexes ... See more keywords
Synthesis of Os Hydride Complexes Supported by the Diarylamido/Bis(phosphine) PNP Ligand and Attempts at Using (PNP)Ru and (PNP)Os Complexes in C–H Borylation Catalysis
Sign Up to like & getrecommendations! Published in 2024 at "Organometallics"
DOI: 10.1021/acs.organomet.4c00388
Abstract: This manuscript describes the synthesis of Os complexes supported by the diarylamido/bis(phosphine) PNP pincer ligand. Compound (PNP)OsH(CO) (3-Os) was prepared by analogy with the previously reported 3-Ru. However, attempts to make (PNP)OsH3 (4-Os) analogously to… read more here.
Keywords: diarylamido bis; borylation; pnp; complexes supported ... See more keywords