Synthesis, Structure, and Reductive Elimination of Cationic Monoarylpalladium(IV) Complexes Supported by a Tripodal Oxygen Ligand
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700326
Abstract: Cationic monoaryl–PdIV complexes supported by the Klaui tripodal ligand [Co(η5-C5H5){P(O)(OEt)2}3]– (LOEt–) were synthesized, and their reductive elimination was studied. Treatment of trans-[Pd(PPh3)2(Ar)(I)] and [{Pd(η2-ppytBu)Cl}2] [ppytBuH = 2-(4-tert-butylphenyl)pyridine] with [AgLOEt] afforded [Pd(Ar)(PPh3)(η2-LOEt)] [Ar = Ph (1),… read more here.
Keywords: complexes supported; loet; elimination; loet pf6 ... See more keywords
Catalytic oxidation of benzene to phenol with hydrogen peroxide over Fe-terpyridine complexes supported on a cation exchange resin
Sign Up to like & getrecommendations! Published in 2018 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2018.08.011
Abstract: Abstract The catalytic activity of [Fe(terpy)2]2+ complexes supported on the cation exchange resins, ([Fe(terpy)2]2+@resin), was investigated for the oxidation of benzene with H2O2 to yield phenol. The catalytic activity of an [Fe(terpy)2]2+@Nafion catalyst for the… read more here.
Keywords: supported cation; resin; complexes supported; oxidation ... See more keywords
Mononuclear nickel (II) and copper (II) coordination complexes supported by bispicen ligand derivatives: Experimental and computational studies
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2016.09.001
Abstract: Abstract The synthesis, characterization and density functional theory calculations of mononuclear Ni and Cu complexes supported by the N,N′-dimethyl-N,N′-bis-(pyridine-2-ylmethyl)-1,2-diaminoethane ligand and its derivatives are reported. The complexes were characterized by X-ray crystallography as well as… read more here.
Keywords: coordination; complexes supported; geometry; ligand derivatives ... See more keywords
Synthesis, characterization, and reactivity of copper complexes supported by the TPMEN ligand framework
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.09.041
Abstract: Abstract Two new Cu(II) complexes supported by nitrogen-rich ligands have been synthesized and characterized by absorption spectroscopy, magnetic moment, and cyclic voltammetry. Complex 1 is supported by the ligand TPMEN (N,N,N′-tris(2-pyridylmethyl)-N′-methylethylenediamine) with two amine and… read more here.
Keywords: reactivity copper; complexes supported; copper complexes; characterization reactivity ... See more keywords
Monomeric zinc(II) amide complexes supported by bidentate, benzannulated phenanthridine amido ligands
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.01.023
Abstract: Abstract The first examples of homoleptic zinc amides (1-Zn and 2-Zn) supported by chelating, benzannulated 4-amidophenanthridine ligands (L1, L2) are reported. The organometallic compounds were characterized fully both in solution (NMR, UV–Vis, electrochemistry, emission spectroscopy)… read more here.
Keywords: zinc amide; monomeric zinc; complexes supported; zinc ... See more keywords
Platinum(II)-Substituted Phenylacetylide Complexes Supported by Acyclic Diaminocarbene Ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00510
Abstract: We introduce phosphorescent platinum aryl acetylide complexes supported by tert-butyl-isocyanide and strongly σ-donating acyclic diaminocarbene (ADC) ligands. The precursor complexes cis-[Pt(CNtBu)2(C≡CAr)2] (4a-4f) are treated with diethylamine, which undergoes nucleophilic addition with one of the isocyanides… read more here.
Keywords: platinum substituted; complexes supported; acyclic diaminocarbene; substituted phenylacetylide ... See more keywords
Bis(tetramethylaluminate) Lanthanide Complexes Supported by Bi- and Tridentate Amidinate Ligands: Performance in Isoprene Polymerization
Sign Up to like & getrecommendations! Published in 2021 at "Organometallics"
DOI: 10.1021/acs.organomet.1c00061
Abstract: The isolable bis(tetramethylaluminate) lanthanide complexes [2-R2,6-XC6H4NC(tBu)(2,6-R12C6H3)]Ln(AlMe4)2 (R1 = R2 = X = Me, Ln = La (1); R1 = R2 = X = Me, Ln = Nd (2); R1 = iPr, R2 = H, X… read more here.
Keywords: supported tridentate; complexes supported; lanthanide complexes; bis tetramethylaluminate ... See more keywords
Comprehensive Experimental and Computational Study of η6-Arene Ruthenium(II) and Osmium(II) Complexes Supported by Sulfur Analogues of the β-Diketiminate Ligand
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00111
Abstract: In comparison to β-diketiminates, a highly exploited class of N,N-chelating ligands, the corresponding β-thioketoiminates, monothio-substituted analogues, have received only minor attention. β-Thioketoiminates are straightforwardly prepared through treatment of an appropriate β-ketoiminate with Lawesson’s reagent. Employing… read more here.
Keywords: complexes supported; comprehensive experimental; computational study; study arene ... See more keywords
A versatile route to homo- and hetero-bimetallic 5f-5f and 3d-5f complexes supported by a redox active ligand framework.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01993a
Abstract: The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium-uranium and rare heterobimetallic uranium-cobalt and uranium-nickel complexes supported by a redox-active dinucleating ligand. read more here.
Keywords: supported redox; complexes supported; versatile route; route homo ... See more keywords
Tungsten and molybdenum dinitrogen complexes supported by a pentadentate tetrapodal phosphine ligand: comparative spectroscopic, electrochemical and reactivity studies.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04212b
Abstract: The tungsten dinitrogen complex [W(N2)(PMe2PPPh2)] (2) (PMe2PPPh2 = [2-({bis[3-(diphenylphosphino)propyl]-phosphino}methyl)-2-methylpropane-1,3-diyl]bis(dimethylphosphine)) is synthesized and characterized by X-ray diffraction as well as IR and NMR spectroscopies, showing strong analogies to its molybdenum analogue [Mo(N2)(PMe2PPPh2)] (1). Whereas cyclic voltammetry… read more here.
Keywords: molybdenum dinitrogen; tungsten molybdenum; dinitrogen complexes; supported pentadentate ... See more keywords
LPdCl2(amine) complexes supported by terphenyl phosphanes: applications in aryl amination reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01354a
Abstract: Despite the excellent catalytic properties display by NHC-Pd-PEPPSI complexes in cross-coupling, phosphane analogs have been barely screened. In this work, we report the synthesis and characterization of a series of LPdCl2(amine) complexes bearing dialkylterphenyl phosphanes… read more here.
Keywords: complexes supported; amine complexes; amination reactions; lpdcl2 amine ... See more keywords