Heteroleptic (N-heterocyclic carbene)–Pd–pyrazole (indazole) complexes: Synthesis, characterization and catalytic activities towards C–C and C–N cross-coupling reactions
Sign Up to like & getrecommendations! Published in 2017 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.3734
Abstract: Eight heteroleptic palladium complexes containing both N-heterocyclic carbenes and NH-heterocycle azoles (pyrazole and indazole) were synthesized and characterized, and their structures were unambiguously confirmed using single-crystal X-ray diffraction. Further investigation of the complexes as catalysts… read more here.
Keywords: heteroleptic heterocyclic; indazole complexes; complexes synthesis; carbene pyrazole ... See more keywords
Ternary Cu(II) complexes: synthesis, structural elucidation, and biological studies (DNA binding, cleavage, antibacterial, cytotoxicity)
Sign Up to like & getrecommendations! Published in 2020 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-020-04140-9
Abstract: The present work focused on the assembly of 2-((2-(4-chlorophenylamino)phenylimino)methyl)-6-methoxyphenol as primary ligand (VBL) and bidentate nitrogen donors, namely 2,2′-bipyridyl (L1), 1,10-phenanthroline (L2), and ethylenediamine (L3) as secondary ligands with Cu(II) ion. The synthesized compounds were… read more here.
Keywords: ternary complexes; synthesis structural; complexes synthesis; structural elucidation ... See more keywords
Some Novel Rare Earth Metal Ions complexes: Synthesis, Characterization, Luminescence and Biocidal Efficiency.
Sign Up to like & getrecommendations! Published in 2020 at "Analytical biochemistry"
DOI: 10.1016/j.ab.2020.113645
Abstract: New lanthanide complexes (1-3) of the general formulae [Ln(L)(NO3)(H2O)] have been synthesized by reaction of Ln(NO3)3.xH2O {Ln = La (1), Sm (2) and Yb (3)} with 2,2'-(((1E,1'E)-thiophene-2,5-diylbis(methaneylylidene))bis(azaneylylidene))diphenol (H2L). Based on elemental analysis and spectroscopic analysis… read more here.
Keywords: earth metal; complexes synthesis; metal ions; novel rare ... See more keywords
Tetradentate platinum(II) complexes: Synthesis, photophysical properties, liquid crystalline characteristics and charge transport behaviour
Sign Up to like & getrecommendations! Published in 2019 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2019.01.026
Abstract: Abstract Three new tetradentate phosphorescent Pt(II) complexes (Pt6, Pt12 and Pt16) with half-disc molecule structure were designed and synthesized, which are based on tetradentate ligands with six alkoxyl chains on the periphery, (6,6′-bis((3′,4′,5′-alkoxy-[1,1′-biphenyl]-4-yl)oxy)-2,2′-bipyridine). All complexes… read more here.
Keywords: platinum complexes; tetradentate platinum; charge transport; liquid crystalline ... See more keywords
Tris dithiocarbamate of Co(III) complexes: Synthesis, characterization, thermal decomposition studies and experimental and theoretical studies on their crystal structures
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2016.12.097
Abstract: Abstract New homoleptic complexes of the form [Co(L 1 ) 3 ] & [Co(L 2 ) 3 ] where L 1 = (ethylaminoethanol dithiocarbamate) 1 and L 2 = (methylaminoethanol dithiocarbamate) 2 have been prepared and characterized… read more here.
Keywords: complexes synthesis; dithiocarbamate iii; iii complexes; tris dithiocarbamate ... See more keywords
Novel Benzimidazole- Platinum(II) Complexes: Synthesis, Characterization, Antimicrobial and Anticancer Activity
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129785
Abstract: Abstract Three new Platinum complexes (1-3) with 2,6-di-tert-butyl-4-(1-phenyl-1H-benzimidazol-2-yl) phenol (L1), N, N-dimethyl-4-(1-phenyl-1H-benzimidazol-2-yl) aniline (L2) and 4-(1H-benzimidazol-2-yl)-N, N-dimethylaniline (L3) were prepared and characterized by FT-IR, NMR and Elemental analyses. The crystal structures of L1, 1 and… read more here.
Keywords: platinum; complexes synthesis; benzimidazole platinum; novel benzimidazole ... See more keywords
A family of 3d-4f Cu-Ln ladder-like complexes: Synthesis, structures and magnetic properties
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114435
Abstract: Abstract A family of rare 2p-3d-4f ladder-like one-chain complexes namely [LnCu(hfac)5NIT-Ph-p-OCH2trz·0.5C6H14]n (Ln = Er (1), Ho (2), Yb (3) ; NIT-Ph-p-OCH2trz = 2-(4-((1H-1,2,4-triazol-1-yl)methoxy)phenyl)-4,4,5,5-tetra- methylimidazoline-1-oxyl-3-oxide; hfac = hexafluoroacetylacetonate) have been successfully synthesized simultaneously through reacting nitronyl nirtroxide radical NIT-Ph-p-OCH2trz with Cu(hfac)2 and… read more here.
Keywords: ladder like; like complexes; synthesis structures; complexes synthesis ... See more keywords
The Cluster Polyazide Complexes: Synthesis, Crystal Structures, and 14N NMR Studies of [{Re3(μ-X)3}(N3)9]3- (X = Br or I).
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01949
Abstract: Azide cluster complexes [{Re3(μ-Br)3}(N3)9]3- and [{Re3(μ-I)3}(N3)9]3- were obtained by reaction of Re3X9 (X = Br or I, respectively) with sodium azide in methanol. The complexes were crystallized as cesium salts of the compositions Cs3[{Re3(μ-Br)3}(N3)9]·H2O (1)… read more here.
Keywords: polyazide complexes; 14n nmr; cluster; complexes synthesis ... See more keywords
Group 10 Metal Dithiolene Bis(isonitrile) Complexes: Synthesis, Structures, Properties, and Reactivity
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00375
Abstract: The reaction of [(Ph2C2S2)2M] (M = Ni2+, Pd2+, Pt2+) with 2 equiv of RN≡C (R = Me (a), Bn (b), Cy (c), tBu (d), 1-Ad (e), Ph (f)) yields [(Ph2C2S2)M(C≡NR)2] (M = Ni2+, 4a–f; M… read more here.
Keywords: bis isonitrile; group metal; complexes synthesis; metal dithiolene ... See more keywords
Aluminabenzene-Rh and -Ir Complexes: Synthesis, Structure, and Application toward Catalytic C-H Borylation.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b11127
Abstract: Aluminabenzene-rhodium and -iridium complexes were synthesized, in which the aluminum atom played as a proximal Lewis acidic site. Based on their structural analysis, aluminabenzene ligand could coordinate to Rh and Ir as a η5-pentadienyl ligand.… read more here.
Keywords: aluminabenzene complexes; borylation; complexes synthesis; aluminabenzene ... See more keywords
Redox-switching of ternary Ni(ii) and Cu(ii) complexes: synthesis, experimental and theoretical studies along with second-order nonlinear optical properties
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj01774g
Abstract: The redox-switching behavior of the title compounds has been probed for the Ni(ii) derivatives using time-resolved spectroelectrochemistry under thin-layer conditions. read more here.
Keywords: experimental theoretical; switching ternary; synthesis experimental; ternary complexes ... See more keywords