Thermally stable dinuclear Co(II) and Zn(II) complexes of tetra-phosphonate and 2,2′-bipyridine
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119750
Abstract: Abstract Two dinuclear phosphonate-based transition metal complexes, [Co2(H6tpmb)2(2,2′-bipy)2(H2O)2] (1) and [Zn2(H6tpmb)2(2,2′-bipy)2] (2), have been synthesized at 60 °C by the reactions of 1,2,4,5-tetrakis(phosphorylmethyl)benzene (H8tpmb) and 2,2′-bipyridine (2,2′-bipy) ligands, with CoCl2·6H2O and Zn(NO3)2·6H2O, respectively. These two complexes… read more here.
Keywords: dinuclear complexes; thermally stable; bipyridine; stable dinuclear ... See more keywords
The enhancement of luminescent properties of Tb 3+ complexes with tetra-1,3-diketone ligands promoted by the tetrathiacalix[4]arene scaffold
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2018.05.084
Abstract: Abstract This is the first report on the synthesis and characterization of tetra-1,3-diketone derivatives of tetrthia- and calix[4]arenes substituted by acetylacetonyl or dipivaloylmethanyl moieties at the upper rim and bearing hydroxyl groups at the lower… read more here.
Keywords: diketone ligands; enhancement luminescent; luminescent properties; diketone ... See more keywords
Gold(I) complexes of tetra-tert-butylcyclotetraphosphane.
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DOI: 10.1039/d2dt00202g
Abstract: The reaction of tetra-tert-butylcyclotetraphosphane cyclo-(PtBu)4 (L) with one to four equivalents of [AuCl(tht)] (tht = tetrahydrothiophene) leads to the formation of gold(I) complexes [(AuCl)nL] (n = 1-4, 1-4) in which the ligand coordinates up to… read more here.
Keywords: gold complexes; tetra tert; tert butylcyclotetraphosphane; complexes tetra ... See more keywords