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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03306
Abstract: 1,3,5-Trimethyl-1,3,5-triazacyclohexane (Me3tach) readily complexes uranium triiodide to form (Me3tach)2UI3. The complex is soluble in THF and arenes and can function as a source of UI3 to form organometallic U(III) complexes. When dissolved in pyridine (py),…
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Keywords:
complexes uranium;
thf;
me3tach;
neptunium plutonium ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04803e
Abstract: σ-Hydrocarbyl complexes of the form [M(η5-PC4Me4)2(μ-η1:η6-CH2Ph)2K(η6-arene)] (M = La, Ce, Pr, U, Np, Pu; arene = benzene or toluene) were synthesised in one-pot reactions from [MI3(THF)4], or [U(BH4)3(toluene)] (M = U). All complexes were examined…
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Keywords:
complexes uranium;
isostructural hydrocarbyl;
neptunium plutonium;
hydrocarbyl phospholide ... See more keywords