Model compound of [FeFe]-hydrogenase active site employing [2Fe–2S] subunit as non-innocent [4Fe–4S] cluster and its proton reduction performance
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DOI: 10.1016/j.ijhydene.2020.02.084
Abstract: Abstract Synthesis of model compound of [FeFe]-hydrogenase active site is a promising and effective method to produce hydrogen. [μ-(SCH(CH2CH3)CH2S)–Fe2(CO)5]2-(κ1-DPPE) (compound 1) and [μ-(SCH(CH2CH3)CH2S)] Fe2(CO)5 (κ1-DPPM) (compound 2) were designed and synthesized. Compared 1 and 2… read more here.
Keywords: reduction; model compound; compound fefe; proton reduction ... See more keywords