Dinuclear organotin compounds carrying naphthylene- and biphenylene-spacer groups
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DOI: 10.1016/j.jorganchem.2020.121344
Abstract: Abstract The reaction of XMg−CH2−Y−CH2−MgX [Y = 2,6−naphthylene (−C10H6−) or 1,1’−biphenylene (−C12H8−); X = Cl or Br] with two molar equivalents of Ph3SnCl or Ph2(Me3SiCH2)SnI gave Ph3Sn−CH2−C10H6−CH2−SnPh3 (1), Ph3Sn−CH2−C12H8−CH2−SnPh3 (2) and Ph2(Me3SiCH2)Sn−CH2−C12H8−CH2−Sn(CH2SiMe3)Ph2 (3), respectively, in good yields. Reaction of… read more here.
Keywords: ch2; c12h8 ch2; dinuclear organotin; compounds carrying ... See more keywords