Synthesis and disassembly of an organometallic polymer comprising redox-active Co4S4 clusters and Janus biscarbene linkers.
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DOI: 10.1039/d2cc00953f
Abstract: Here, we show for the first time that main-chain organometallic polymers (MCOPs) can be prepared from Janus N-heterocyclic carbene (NHC) linkers and polynuclear cluster nodes. The crosslinked framework Co4S4-MCOP is synthesized via ligand displacement reactions… read more here.
Keywords: comprising redox; polymer comprising; co4s4; synthesis disassembly ... See more keywords