How to Compute Density Fluctuations at the Nanoscale
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DOI: 10.1021/acs.jctc.4c01047
Abstract: The standard definition of particle number fluctuations based on point-like particles neglects the excluded volume effect. This leads to a large and systematic finite-size scaling and an unphysical surface term in the isothermal compressibility. We… read more here.
Keywords: size; compute density; finite size; density fluctuations ... See more keywords