Nitrogen-Centered Concave Molecules with Double Fused Pentagons.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b01861
Abstract: Distinctive concave compounds bearing a nitrogen core and double fused pentagons were synthesized with a palladium-catalyzed intramolecular coupling of 1-chloro-8 H-indolo[3,2,1- de]acridine as the key step. Structural analysis confirmed the formation of bowl-shaped molecules. Experimental… read more here.
Keywords: double fused; molecules double; nitrogen centered; fused pentagons ... See more keywords
Synthesis of a chiral metallo-capsule composed of concave molecules and chirogenesis upon fullerene binding.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc02341a
Abstract: An enantiopure molecular capsule was synthesized quantitatively using complexation of four phosphangulenes as concave molecules with four Zn2+ ions and applied to fullerene binding and chirogenesis. The capsule encapsulated selectively fullerene and its derivatives based… read more here.
Keywords: synthesis chiral; capsule; metallo capsule; chiral metallo ... See more keywords