A concerted addition mechanism in [Hmim]Br-triggered thiol–ene reactions: a typical “ionic liquid effect” revealed by DFT and experimental studies
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DOI: 10.1039/c8nj05674a
Abstract: The π+–π and H-bond interactions between [Hmim]Br and substrates promote a special one-step addition mechanism in thiol–ene reactions. read more here.
Keywords: concerted addition; ene reactions; thiol ene; addition mechanism ... See more keywords
Concerted addition of aldehydes to the singlet biradical [P(μ-NTer)]2.
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DOI: 10.1039/d2dt02229j
Abstract: The reaction of the singlet biradical [P(μ-NTer)]2 with various aldehydes selectively yielded the corresponding [2.1.1]-bicyclic addition products in a very fast reaction. All products were fully characterized, including by NMR and vibrational spectroscopy as well… read more here.
Keywords: addition; reaction; addition aldehydes; biradical nter ... See more keywords