Autoxidized Oleic Acid Bifunctional Macro Peroxide Initiators for Free Radical and Condensation Polymerization. Synthesis and Characterization of Multiblock Copolymers
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Polymers and the Environment"
DOI: 10.1007/s10924-019-01536-6
Abstract: Autoxidation of unsaturated fatty acids gives fatty acid macroperoxide initiators containing two functionalities which can lead to free radical and condensation polymerizations in a single pot. The oleic acid macroperoxide initiator obtained by ecofriendly autoxidation… read more here.
Keywords: radical condensation; condensation polymerization; oleic acid; free radical ... See more keywords
Regioselective Condensation Polymerization of Propargylic Electrophiles Enabled by Catalytic Element-Cupration.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c05524
Abstract: Here, we report a set of new polymerization reactions enabled by the 1,2-regioselective hydro- and silylcupration of enyne-type propargylic electrophiles. Highly regioregular head-to-tail poly(2-butyne-1,4-diyl)s (HT-PBD), bearing either methyl or silylmethyl side chains, are synthesized for… read more here.
Keywords: regioselective condensation; condensation polymerization; electrophiles enabled; polymerization propargylic ... See more keywords