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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.8b03965
Abstract: Several dracaenones were synthesized in enantiopure forms for the first time. The key chiral center at C-7 was installed with well-defined stereochemistry using either an Evans aldol condensation or a chiral oxidant-mediated asymmetric epoxidation, while…
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Keywords:
synthesis configuration;
configuration natural;
natural dracaenones;