Configurational landscape of chiral iron(ii) bis(phosphane) complexes.
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DOI: 10.1039/c9dt04821a
Abstract: The reaction of a chiral [FeH(η2-H2){(R,R)-Me-DuPhos}2]+ ((R,R)-Me-DuPhos = (-)-1,2-bis[(2R,5R)-2,5-dimethylphospholano]benzene) complex with ethers and halides is investigated by NMR techniques. From this study, it is apparent that dihydrogen ligand exchange by poorly-coordinating donor molecules, such as… read more here.
Keywords: configurational landscape; landscape chiral; bis; duphos ... See more keywords