Chromatographic approach to study the configurational stability of Ni(II) complexes of amino-acid Schiff bases possessing stereogenic nitrogen.
Sign Up to like & getrecommendations! Published in 2019 at "Chirality"
DOI: 10.1002/chir.23059
Abstract: Herein, we disclose the design of a model Ni(II) complex of glycine Schiff base possessing single-nitrogen stereogenic center, which was successfully used for high-performance liquid chromatography (HPLC)-assisted assessment of its configurational stability. The major finding… read more here.
Keywords: schiff; nitrogen; chromatographic approach; configurational stability ... See more keywords
Configurational Stability of [5]Helicenes.
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DOI: 10.1021/acs.orglett.7b01461
Abstract: A series of [5]helicenes difunctionalized in the fjord region with either fluoro, methoxy, or methyl groups was synthesized via photochemical and benzylic coupling route. Resolution of each compound into enantiomers and determination of the Gibbs… read more here.
Keywords: stability helicenes; stability; configurational stability;