Development of Configurationally Labile Biaryl Reagents for Atropisomer Synthesis
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202400402
Abstract: Axially chiral biaryl scaffolds are important in pharmaceuticals, natural products, and asymmetric synthesis. Atroposelective ring‐opening of configurationally labile biaryl reagents via dynamic kinetic asymmetric transformation provides a valuable approach to access axially chiral biaryl atropisomers.… read more here.
Keywords: development configurationally; configurationally labile; labile biaryl; biaryl reagents ... See more keywords
Absolute configuration retention of a configurationally labile ligand during dynamic processes of thiolate protected gold clusters†
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc01702k
Abstract: Monolayer protected metal clusters are dynamic nanoscale objects. For example, the chiral Au38(2-PET)24 cluster (2-PET: 2-phenylethylthiolate) racemizes at moderate temperature. In addition, ligands and metal atoms can easily exchange between clusters. Such processes are important… read more here.
Keywords: configurationally labile; au38 pet; ligand; cluster ... See more keywords