Phase equilibria and conformational behavior of dendrimers in porous media: Towards chromatographic analysis of dendrimers.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2021.09.177
Abstract: HYPOTHESIS The intricate entropy-enthalpy interplay of dendrimers confined in pores affects their conformation and retention in the porous stationary phase. This work aims at providing important insights into its impacts on partitioning and chromatographic separation… read more here.
Keywords: phase equilibria; dendrimers porous; behavior dendrimers; equilibria conformational ... See more keywords
The conformational behavior and structure of monosubstituted-1,3,5-trisilacyclohexanes: 1-N,N-dimethylamino-1,3,5-trisilacyclohexane
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DOI: 10.1016/j.molstruc.2020.129046
Abstract: Abstract 1-dimethylamino-1,3,5-trisilacyclohexane was synthesized and its structure and conformational properties have been determined by gas electron diffraction (GED) and quantum chemical (QC) calculations. The molecule may exist in 3 or 4 forms differing from each… read more here.
Keywords: structure monosubstituted; behavior structure; monosubstituted trisilacyclohexanes; dimethylamino trisilacyclohexane ... See more keywords
NMR-based investigations of acyl-functionalized piperazines concerning their conformational behavior in solution
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DOI: 10.1039/c8ra09152h
Abstract: Selected N-benzoylated piperazine compounds were synthesized to study their conformational behavior using temperature-dependent 1H NMR spectroscopy. All investigated piperazines occur as conformers at room temperature resulting from the restricted rotation of the partial amide double… read more here.
Keywords: acyl functionalized; based investigations; functionalized piperazines; conformational behavior ... See more keywords
Effect of Counterion Valence on Conformational Behavior of Spherical Polyelectrolyte Brushes Confined between Two Parallel Walls
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DOI: 10.3390/polym10040363
Abstract: We study the conformational behavior of spherical polyelectrolyte brushes in the presence of monovalent and trivalent counterions in a confined environment. The confinement is exerted by two parallel walls on the brushes. The enhancement of… read more here.
Keywords: trivalent counterions; spherical polyelectrolyte; polyelectrolyte brushes; behavior spherical ... See more keywords