Anchoring H-Bond Donating/Accepting Pyrrolic Derivatives on Preorganized Scaffolds: Conformationally Switchable Bipedal/Tripodal and Locked Molecular Cage Ionophores for Potentiometric Sensing of Phosphate and Fluoride.
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DOI: 10.1021/acs.analchem.2c02024
Abstract: The ionophore properties of a myriad of conformationally switchable bipedal/tripodal receptors and locked molecular cages were evaluated here for the first time to fabricate potentiometric sensors for the determination of environmentally important phosphate and fluoride.… read more here.
Keywords: phosphate; bipedal tripodal; switchable bipedal; locked molecular ... See more keywords
Engineering a Conformationally Switchable Artificial Metalloprotein.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08885
Abstract: Many naturally occurring metalloenzymes are gated by rate-limiting conformational changes, and there exists a critical interplay between macroscopic structural rearrangements of the protein and subatomic changes affecting the electronic structure of embedded metallocofactors. Despite this… read more here.
Keywords: artificial metalloprotein; engineering conformationally; switchable artificial; conformationally switchable ... See more keywords