Simultaneous Tunneling Control in Conformer-Specific Reactions
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c09026
Abstract: We present here a new example of chemical reactivity governed by quantum tunneling, which also highlights the limitations of the classical theories. The syn and anti conformers of a triplet 2-formylphenylnitrene, generated in a nitrogen… read more here.
Keywords: specific reactions; control; simultaneous tunneling; tunneling control ... See more keywords
Conformer-specific photochemistry imaged in real space and time
Sign Up to like & getrecommendations! Published in 2021 at "Science"
DOI: 10.1126/science.abk3132
Abstract: Description Conformer-specific dynamics Conformation-dependent dynamics play an important role in organic chemistry syntheses such as electrocyclic reactions, as well as in biological processes such as protein folding. However, current time-resolved experimental methods struggle to distinguish… read more here.
Keywords: ring opening; conformer specific; chemistry; time ... See more keywords