Pd-Catalyzed C-O Bond Formation Enabling the Synthesis of Congested N,N,O-Trisubstituted Hydroxylamines.
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DOI: 10.1021/acs.orglett.2c02975
Abstract: A Pd-catalyzed C-O cross-coupling of O-acyl hydroxylamines and tertiary or secondary alkyl electrophiles was reported without the cleavage of the rather fragile N-O bond. The described strategy provides direct access to congested N,N,O-trisubstituted hydroxylamines bearing… read more here.
Keywords: trisubstituted hydroxylamines; catalyzed bond; bond formation; congested trisubstituted ... See more keywords