The Integral Role of Conjugate Acids in Brønsted Base‐Catalyzed Regiodivergent Synthesis
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DOI: 10.1002/cctc.202400405
Abstract: Catalyst‐controlled diversity‐oriented synthesis (CatDOS) is an important research area for expanding molecular complexities and achieving high atomic economics. Many regiodivergent syntheses have been achieved through metal catalysis, covalent organocatalysis, and non‐covalent organocatalysis by controlling the… read more here.
Keywords: nsted base; regioselectivity; organocatalysis; conjugate acids ... See more keywords
Experimental and Computational Gas Phase Acidities of Conjugate Acids of Triazolylidene Carbenes: Rationalizing Subtle Electronic Effects.
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DOI: 10.1021/jacs.7b05229
Abstract: In recent years, triazolylidene carbenes have come to the forefront as important organocatalysts for a wide range of reactions. The fundamental properties of these species, however, remain largely unknown. Herein, the gas phase acidities have… read more here.
Keywords: phase acidities; gas phase; triazolylidene carbenes; conjugate acids ... See more keywords