End-reactive poly(tetrahydrofuran) for functionalization and graft copolymer synthesis via a conjugate substitution reaction
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DOI: 10.1038/s41428-019-0258-4
Abstract: Abstract α-(Chloromethyl)acryloyl cation, prepared from the corresponding acyl chloride and silver triflate, was used as an initiator for the living, cationic ring-opening polymerization of tetrahydrofuran. The α-end of the resulting poly(tetrahydrofuran) has an α-(chloromethyl)acrylate skeleton,… read more here.
Keywords: end; graft copolymer; conjugate substitution;
Conjugate substitution and addition of α-substituted acrylate: a highly efficient, facile, convenient, and versatile approach to fabricate degradable polymers by dynamic covalent chemistry
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DOI: 10.1039/c7py02114c
Abstract: Polycondensation of bis[α-(halomethyl)acrylate] and dithiols, dicarboxylic acids, primary monoamines, and bisphenols via conjugate substitution yielded a series of poly(conjugated ester)s with acryloyl groups in the backbones. In the case of a dithiol monomer, a polar… read more here.
Keywords: chemistry conjugate; chemistry; addition; conjugate substitution ... See more keywords