A High Conductivity 1D π–d Conjugated Metal–Organic Framework with Efficient Polysulfide Trapping‐Diffusion‐Catalysis in Lithium–Sulfur Batteries
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202108835
Abstract: The shuttling behavior and sluggish conversion kinetics of the intermediate lithium polysulfides (LiPS) represent the main obstructions to the practical application of lithium–sulfur batteries (LSBs). Herein, a 1D π–d conjugated metal–organic framework (MOF), Ni‐MOF‐1D, is… read more here.
Keywords: conjugated metal; lithium sulfur; sulfur; metal organic ... See more keywords
Synthesizing Cr-Based Two-Dimensional Conjugated Metal-Organic Framework Through On-Surface Substitution Reaction.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202207877
Abstract: A single-layer Cr3 (HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene) conjugated metal-organic framework (c-MOF) is synthesized under ultrahigh vacuum conditions by substituting Cr for Ni in Ni3 (HITP)2 template. As revealed by low-temperature scanning tunneling microscopy and scanning tunneling spectroscopy,… read more here.
Keywords: organic framework; substitution reaction; conjugated metal; metal organic ... See more keywords
Two-dimensional d-π conjugated metal-organic framework based on hexahydroxytrinaphthylene
Sign Up to like & getrecommendations! Published in 2020 at "Nano Research"
DOI: 10.1007/s12274-020-2874-x
Abstract: The development of new two-dimensional (2D) d-π conjugated metal-organic frameworks (MOFs) holds great promise for the construction of a new generation of porous and semiconductive materials. This paper describes the synthesis, structural characterization, and electronic… read more here.
Keywords: dimensional conjugated; mof; metal organic; two dimensional ... See more keywords
Two-Dimensional Conjugated Metal-Organic Frameworks for Electrocatalysis: Opportunities and Challenges.
Sign Up to like & getrecommendations! Published in 2022 at "ACS nano"
DOI: 10.1021/acsnano.1c10544
Abstract: A highly effective electrocatalyst is the central component of advanced electrochemical energy conversion. Recently, two-dimensional conjugated metal-organic frameworks (2D c-MOFs) have emerged as a class of promising electrocatalysts because of their advantages including 2D layered… read more here.
Keywords: two dimensional; dimensional conjugated; organic frameworks; conjugated metal ... See more keywords
Dual-Redox-Sites Enable Two-Dimensional Conjugated Metal-Organic Frameworks with Large Pseudocapacitance and Wide Potential Window.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c03039
Abstract: Advanced supercapacitor electrodes require the development of materials with dense redox sites embedded into conductive and porous skeletons. Two-dimensional (2D) conjugated metal-organic frameworks (c-MOFs) are attractive supercapacitor electrode materials due to their high intrinsic electrical… read more here.
Keywords: dimensional conjugated; redox sites; redox; metal organic ... See more keywords
Interfacial Synthesis of Layer-Oriented 2D Conjugated Metal-Organic Framework Films toward Directional Charge Transport.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c05051
Abstract: The development of layer-oriented two-dimensional conjugated metal-organic frameworks (2D c-MOFs) enables access to direct charge transport, dial-in lateral/vertical electronic devices, and the unveiling of transport mechanisms but remains a significant synthetic challenge. Here we report… read more here.
Keywords: charge transport; layer; transport; layer oriented ... See more keywords
Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity.
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DOI: 10.1021/jacs.1c12596
Abstract: The dimensional reduction of solids into smaller fragments provides a route to achieve new physical properties and gain deeper insight into the extended parent structures. Here, we report the synthesis of CuTOTP-OR (TOTPn- = 2,3,6,7-tetraoxidotriphenylene),… read more here.
Keywords: charge transport; conjugated metal; synthesis; metal organic ... See more keywords
Two-dimensional π-conjugated metal bis(dithiolene) nanosheets as promising electrocatalysts for carbon dioxide reduction: a computational study
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry A"
DOI: 10.1039/c9ta02271f
Abstract: Two-dimensional π-conjugated metal bis(dithiolene) nanosheets exhibit high carbon dioxide reduction electrocatalytic activity. read more here.
Keywords: dithiolene nanosheets; dimensional conjugated; conjugated metal; bis dithiolene ... See more keywords
Synthesis of vildagliptin conjugated metal nanoparticles for type II diabetes control: targeting the DPP-IV enzyme
Sign Up to like & getrecommendations! Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/d0nj04202a
Abstract: Diabetes is one of the most prevalent diseases worldwide. Vildagliptin is a drug which overcomes the existing problems of anti-diabetic drugs. However, the short half-life (2–3 h) of vildagliptin remains an important concern. Recently there… read more here.
Keywords: synthesis vildagliptin; metal nanoparticles; vildagliptin; drug ... See more keywords
Salicylaldehydate coordinated two-dimensional-conjugated metal-organic frameworks.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06283f
Abstract: A novel class of copper-based 2D-c-MOF was synthesized from 1,3,5-triformylphloroglucinol using green mechano-chemistry. Herein, metal coordination with the salicylaldehyde functional moiety was explored for the first time in MOFs. Moreover, an intrinsic semiconductive copper-based SA-MOF… read more here.
Keywords: coordinated two; two dimensional; dimensional conjugated; conjugated metal ... See more keywords
Bimetallic conjugated metal-organic frameworks as bifunctional electrocatalysts for overall water splitting.
Sign Up to like & getrecommendations! Published in 2023 at "Nanoscale"
DOI: 10.1039/d3nr00938f
Abstract: Stable, high-efficiency, and highly active electrocatalysts are critical for the conversion of renewable energy through overall water splitting. Our first-principles calculations identify two-dimensional conjugated metal-organic frameworks (2D c-MOFs) with dual metal sites as promising candidates… read more here.
Keywords: organic frameworks; conjugated metal; metal organic; water splitting ... See more keywords