Cooperative Bond Activation and Catalytic CO2 Functionalization with a Geometrically Constrained Bis(silylene)-Stabilized Borylene.
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DOI: 10.1021/jacs.3c00949
Abstract: Metal-ligand cooperativity has emerged as an important strategy to tune the reactivity of transition-metal complexes for the catalysis and activation of small molecules. Studies of main-group compounds, however, are scarce. Here, we report the synthesis,… read more here.
Keywords: bis silylene; constrained bis; geometrically constrained; activation ... See more keywords