Group 4 constrained geometry complexes for olefin (co)polymerisation
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DOI: 10.1016/j.mcat.2020.110872
Abstract: Abstract We report the synthesis and characterisation of eight constrained geometry complexes, with variation of the amido fragment, ansa-bridge, permethylindenyl group, metal centre and initiator groups from the parent complex Me2SB(tBuN,I*)TiCl2. These complexes have been… read more here.
Keywords: group constrained; geometry complexes; geometry; constrained geometry ... See more keywords
Quantitative structure-property relationship study of constrained geometry catalysts for olefin polymerization
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DOI: 10.1039/d4nj00229f
Abstract: The quantitative structure-property relationship (QSPR) of constrained geometry catalyst (CGC) has been analyzed by combining density functional theory (DFT) and multivariate linear regression (MLR). QSPR models for the reaction energy... read more here.
Keywords: constrained geometry; structure property; property relationship; geometry ... See more keywords