Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment.
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DOI: 10.1039/d4dt02131b
Abstract: Two pairs of chiral enantiomers D/L-Dy(PMP)3·2H2O (D-1/L-1) and D/L-Yb(PMP)3·2H2O (D-2/L-2) were synthesized by the introduction of enantiomerically pure D/L-PMP (PMP = (phosphonomethyl)proline) ligands into lanthanide coordination chemistry. The chiral characteristics of these products were confirmed… read more here.
Keywords: trigonal prismatic; ions trigonal; prismatic coordination; constructed lanthanide ... See more keywords