2D and 3D metal-organic frameworks constructed with a mechanically rigidified [3]rotaxane ligand.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01198k
Abstract: A mechanically interlocked [3]rotaxane was newly designed, synthesized, and employed as a ligand for constructing metal-organic frameworks (MOFs). The nano-confinement by macrocycles forces the soft bis-isophthalate axle into a pseudo-rigid conformation and coordinates to zinc(II)… read more here.
Keywords: rotaxane; organic frameworks; metal organic; constructed mechanically ... See more keywords
A hydrogen-bonded polymer constructed from mechanically interlocked, suit[1]ane monomers
Sign Up to like & getrecommendations! Published in 2020 at "Canadian Journal of Chemistry"
DOI: 10.1139/cjc-2020-0002
Abstract: A T-shaped 2,4,7-substituted benzimidazolium “axle” with two ester functionalities and a 24-membered crown ether “wheel” with appendages containing terminal olefin groups were threaded — axle throu... read more here.
Keywords: hydrogen bonded; polymer constructed; mechanically interlocked; constructed mechanically ... See more keywords