Diastereoselective Construction of Eight-Membered Carbocycles through Palladium-Catalyzed C(sp3)-H Functionalization.
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DOI: 10.1021/acs.orglett.0c04244
Abstract: A palladium-catalyzed cross-coupling reaction of 2-alkylphenyl bromides with biphenylene has been developed. The reactions formed eight-membered carbocycles through C(sp3)-H activation and the formation of two C-C bonds, and the chiral products were obtained with excellent… read more here.
Keywords: construction eight; membered carbocycles; palladium catalyzed; eight membered ... See more keywords