Construction of N-Heterocyclic Systems Containing a Fully Substituted Allylic Carbon by Palladium/Phosphine Catalysis.
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DOI: 10.1021/acs.orglett.8b03127
Abstract: The unique cyclization of benzamide derivatives that contain an alkyne by a Pd(0)/dialkyl(biaryl)phosphine catalytic system is reported. The reaction efficiently provides a variety of six-membered N-heterocyclic compounds that contain a fully substituted carbon center without… read more here.
Keywords: fully substituted; carbon; phosphine; systems containing ... See more keywords