Construction and magnetic properties of cobalt(II) and manganese(II) coordination polymers based on N-heterocyclic carboxylate bifunctional ligands
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120054
Abstract: Abstract Four novel coordination polymers, namely, [Co(L1)Cl(H2O)]n (1), [Mn(L1)Cl(H2O)]n·nH2O (2), [Co3(L2)2(H2O)2]n·nCH3CN·nH2O (3), [Mn3(L2)2(H2O)12]n·1.5nH2O (4) were solvothermally constructed by two N-heterocyclic carboxylate bifunctional ligands, 1-(4-carboxylphenyl)-3-(prazin-2-yl)-1H-1,2,4-triazole (HL1) and 5-(2,3-dicarboxylphenoxy)nicotic acid (H3L2). Compounds 1, 2 and 4 exhibit… read more here.
Keywords: construction magnetic; heterocyclic carboxylate; bifunctional ligands; coordination polymers ... See more keywords
Construction of a magnetic chiral coordination polymer based on a semi-rigid carboxylic acid
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2018.1444161
Abstract: Abstract A 2-D chiral entangled coordination polymer, {Mn3(2,2′-bpy)2(3-cpta)2·H2O}n (1) (3-H3cpta=3-(3′-carboxyphenoxy)phthalic acid, 2,2′-bpy=2,2′-bipyridine), has been synthesized via the solvothermal method. X-ray diffraction analysis reveals that 1 consists of one right-handed helical chain and one wavelike 2-D… read more here.
Keywords: construction magnetic; coordination; magnetic chiral; coordination polymer ... See more keywords