Catalytic asymmetric construction of 1,5-remote Si- and C-stereocenters via desymmetrizing ene reaction of bis(methallyl)silanes
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DOI: 10.1039/d5sc01054c
Abstract: The catalytic enantioselective synthesis of chiral silanes has long been a challenging pursuit. Achieving simultaneous construction of remote Si- and C-stereogenic centers in an acyclic molecule via desymmetrization is particularly difficult. Herein, we realized an… read more here.
Keywords: construction remote; ene reaction; reaction bis; methallyl silanes ... See more keywords