(α-Diimine)nickel Complexes That Contain Menthyl Substituents: Synthesis, Conformational Behavior, and Olefin Polymerization Catalysis
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DOI: 10.1021/acs.organomet.7b00283
Abstract: We describe the synthesis and coordination chemistry of the (1R,2S,5R)-menthyl-substituted N,N′-diaryl-α-diimine ligands N,N′-(2-Men-4-Me-Ph)2-BIAN (L1, Men = menthyl, BIAN = bis(imino)acenaphthene) and N,N′-(2-Men-4,6-Me2-Ph)2-BIAN (L2), the conformational properties of these ligands and their metal complexes, and the… read more here.
Keywords: polymerization; complexes contain; nickel complexes; contain menthyl ... See more keywords