Molybdenum‐ and tungsten‐containing formate dehydrogenases and formylmethanofuran dehydrogenases: Structure, mechanism, and cofactor insertion
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DOI: 10.1002/pro.3498
Abstract: An overview is provided of the molybdenum‐ and tungsten‐containing enzymes that catalyze the interconversion of formate and CO2, focusing on common structural and mechanistic themes, as well as a consideration of the manner in which… read more here.
Keywords: tungsten containing; cofactor; containing formate; molybdenum tungsten ... See more keywords
Multiple electron transfer pathways of tungsten-containing formate dehydrogenase in direct electron transfer-type bioelectrocatalysis.
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DOI: 10.1039/d2cc01541b
Abstract: Tungsten-containing formate dehydrogenase from Methylorubrum extroquens AM1 (FoDH1)-a promising biocatalyst for the interconversion of carbon dioxide/formate and nicotine adenine dinucleotide (NAD+)/NADH redox couples-was investigated using structural biology and bioelectrochemistry. FoDH1 is reported to be an… read more here.
Keywords: transfer; formate dehydrogenase; electron transfer; containing formate ... See more keywords
The Mechanism of Metal-Containing Formate Dehydrogenases Revisited: The Formation of Bicarbonate as Product Intermediate Provides Evidence for an Oxygen Atom Transfer Mechanism
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DOI: 10.3390/molecules28041537
Abstract: Mo/W-containing formate dehydrogenases (FDH) catalyzed the reversible oxidation of formate to carbon dioxide at their molybdenum or tungsten active sites. While in the reaction of formate oxidation, the product is CO2, which exits the active… read more here.
Keywords: transfer; formate dehydrogenases; formate; bicarbonate ... See more keywords