Iridium-Catalyzed Hydrosilylation of Sulfur-Containing Olefins.
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DOI: 10.1021/acs.orglett.7b02940
Abstract: Hydrosilylation of various sulfur-containing olefins with (RO)3SiH has been achieved using iridium catalysts [IrX(cod)]2 (X = Cl, SPh). The catalysis is applicable to the chemoselective hydrosilylation of thioacetate, which enables the preparation of an industrially… read more here.
Keywords: catalyzed hydrosilylation; iridium catalyzed; containing olefins; sulfur containing ... See more keywords