Activation of Alkynes by a Redox-Active Carboranyl Diphosphine and Formation of Boron-Containing Phosphacycles.
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DOI: 10.1021/acs.inorgchem.2c02919
Abstract: In this work, we report the reactivity of the carboranyl diphosphine, 1-PtBu2-2-PiPr2-C2B10H10, with terminal alkynes, resulting in the formation of boron-containing phosphacycles. The reported system combines the nucleophilic activation of electron-deficient terminal alkynes via electron-rich… read more here.
Keywords: boron containing; containing phosphacycles; formation boron; activation ... See more keywords