A Novel Ag(I)-Containing Polyoxometalate-Based MOF for Visible-Light-Driven Water Oxidation
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Cluster Science"
DOI: 10.1007/s10876-019-01703-8
Abstract: A novel 3D Ag(I)-containing polyoxometalate-based MOF of H17[Ag9(AgH8W11O44)2(BPY)9]·2.5H2O (WAg–BPY; BPY = 4,4′-bipyridine) has been solvothermally synthesized, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. WAg–BPY exhibits highly… read more here.
Keywords: polyoxometalate based; novel containing; wag bpy; containing polyoxometalate ... See more keywords
A Copper-Containing Polyoxometalate-Based Metal-Organic Framework as an Efficient Catalyst for Selective Catalytic Oxidation of Alkylbenzenes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03741
Abstract: A copper-containing polyoxometalate-based metal-organic framework (POMOF), CuI12Cl2(trz)8[HPW12O40] (HENU-7, HENU = Henan University; trz = 1,2,4-triazole), has been successfully synthesized and well-characterized. In addition, the excellent catalytic ability of HENU-7 has been proved by the selective… read more here.
Keywords: polyoxometalate based; oxidation; copper containing; metal ... See more keywords
Pentadecanuclear Fe-Containing Polyoxometalate Catalyst for Visible-Light-Driven Generation of Hydrogen.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00267
Abstract: The structurally new, carbon-free pentadecanuclear Fe-containing polyoxometalate, Na21[NaFe15(OH)12(PO4)4(A-α-SiW9O34)4]·85H2O (Na21-Fe15P4(SiW9)4), was synthesized using a facile one-pot, solution-based synthetic approach and systematically characterized by various spectroscopic techniques. Single-crystal X-ray diffraction reveals that the title complex is composed… read more here.
Keywords: hydrogen; fe15p4 siw9; polyoxometalate catalyst; containing polyoxometalate ... See more keywords