Controlled Assembly of Ru-Containing Polyoxometalates for Photocatalytic Activity of the Primary Amine Coupling Reaction.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00718
Abstract: Three Ru-induced structural interconversion polyoxometalates (POMs), Na13H5[Ru4(H2O)2(Cl)2(WO2)4(AsW9O33)4]·43H2O (1), K5Na9H8[Ru2(WO2)4(AsW9O33)4]·50H2O (2), and KNa13H14[(WO2)4(AsW9O33)4]·34H2O (3), were successfully synthesized and thoroughly characterized. Interconversion of structures was accomplished by changing the number of active sites for compounds 1-3. All… read more here.
Keywords: containing polyoxometalates; reaction; coupling reaction; controlled assembly ... See more keywords
Assembly Mechanism of Zr-Containing and Other TM-Containing Polyoxometalates.
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DOI: 10.1021/acs.inorgchem.7b00096
Abstract: The mechanism by which Zr-substituted and other transition metal-substituted polyoxometalates (POMs) form covalently linked dimers has been analyzed by means of static density functional theory (DFT) calculations with a continuous solvent model as well as… read more here.
Keywords: zriv; energy; containing containing; mechanism containing ... See more keywords
Peroxo-Cerium(IV)-Containing Polyoxometalates: [CeIV6(O2)9(GeW10O37)3]24-, a Recyclable Homogeneous Oxidation Catalyst.
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DOI: 10.1021/acs.inorgchem.9b01164
Abstract: The class of peroxo-cerium-containing polyoxometalates has been discovered via the synthesis of the 9-peroxo-6-cerium(IV)-containing 30-tungsto-3-germanate, [CeIV6(O2)9(GeW10O37)3]24- (1). Polyanion 1 consists of a cyclic [Ce6(O2)9]6+ assembly that is stabilized by three dilacunary [GeW10O37]10- Keggin fragments. The… read more here.
Keywords: gew10o37; cerium; peroxo; peroxo cerium ... See more keywords
Induced salt-responsive circularly polarized luminescence of hybrid assemblies based on achiral Eu-containing polyoxometalates.
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DOI: 10.1039/c7cc01586k
Abstract: The first circularly polarized luminescence of achiral Eu-containing polyoxometalates (POMs) was realized by electrostatic assembly with a diblock copolymer containing bulky chiral pendants, and was unexpectedly enhanced by NaCl. The induced chirality is attributed to… read more here.
Keywords: circularly polarized; induced salt; polarized luminescence; containing polyoxometalates ... See more keywords