9-Cobalt(II)-Containing 27-Tungsto-3-germanate(IV): Synthesis, Structure, Computational Modeling, and Heterogeneous Water Oxidation Catalysis.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01495
Abstract: The 9-cobalt(II)-containing trimeric, cyclic polyanion [Co9(OH)3(H2O)6(PO4)2(B-α-GeW9O34)3]21- (1) was synthesized in an aqueous phosphate solution at pH 8 and isolated as a hydrated mixed sodium-cesium salt. Polyanion 1 was structurally and compositionally characterized in the solid… read more here.
Keywords: containing tungsto; water oxidation; cobalt containing;
Lanthanide-Containing 22-Tungsto-2-germanates [Ln(GeW11O39)2]13-: Synthesis, Structure, and Magnetic Properties.
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DOI: 10.1021/acs.inorgchem.9b03271
Abstract: We report on the synthesis and structural characterization of two series of lanthanide-containing 22-tungsto-2-germanates. The first series corresponds to a family of polyanions with the formula [Ln(β2-GeW11O39)2]13- (LnIII = La (1), Ce (2), Pr (3),… read more here.
Keywords: gew11o39; tungsto germanates; structure; lanthanide containing ... See more keywords