Lemniscular carbon nanohoops with contiguous conjugation from planar chiral [2.2]paracyclophane: influence of the regioselective synthesis on topological chirality
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DOI: 10.1039/d2sc06825g
Abstract: We report herein the regioselective synthesis of all-carbon lemniscular nanohoops bis-po-CC and bis-pm-TC by the rational control of ring closures at the different positions of planar chiral tetrasubstituted [2.2]paracyclophane. Topological analyses reveal that bis-pm-TC is… read more here.
Keywords: carbon; paracyclophane; contiguous conjugation; regioselective synthesis ... See more keywords