Continuous synthesis of 5-hydroxymethylfurfural using deep eutectic solvents and its kinetic study in microreactors
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2019.123580
Abstract: Abstract A novel route to decompose glucose to 5-hydroxymethylfurfural (5-HMF) in microreactors with the use of deep eutectic solvents (DESs) was reported. For the catalytic mechanism, synergistic effects between quaternary ammonium ionic liquids (i.e., a… read more here.
Keywords: using deep; hydroxymethylfurfural using; continuous synthesis; synthesis hydroxymethylfurfural ... See more keywords
Continuous synthesis of isobutylaluminoxanes in a compact and integrated approach
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.131750
Abstract: Abstract We present a 3D-printed continuous flow platform for controllable synthesis of isobutylaluminoxanes (IBAO), an effective olefin polymerization co-catalyst, via the highly exothermic hydrolytic reaction of triisobutylaluminum (TIBA). This platform encompasses modules of mixing and… read more here.
Keywords: compact integrated; synthesis; synthesis isobutylaluminoxanes; isobutylaluminoxanes compact ... See more keywords
Continuous synthesis of UiO-66 in microreactor: Pursuing the optimum between intensified production and structural properties
Sign Up to like & getrecommendations! Published in 2017 at "Materials Letters"
DOI: 10.1016/j.matlet.2017.02.091
Abstract: Abstract The increasing demand for MOFs can only be satisfied by establishing robust and reproducible synthesis routes which allow a profitable scale-up of the requested materials while preserving their textural properties and stability. A scalable… read more here.
Keywords: synthesis uio; uio microreactor; continuous synthesis; microreactor pursuing ... See more keywords
Continuous Synthesis of Methanol from Methane and Steam over Copper-Mordenite
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c04592
Abstract: One-step methane-to-methanol conversion is a “dream reaction” for chemists. In this Letter, continuous direct conversion of methane into methanol with steam under mild conditions using Cu(II)-excha... read more here.
Keywords: methanol methane; methanol; methane; synthesis methanol ... See more keywords
Halide-Free Continuous Synthesis of Hydrophobic Ionic Liquids
Sign Up to like & getrecommendations! Published in 2022 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.2c02871
Abstract: Herein, we present a novel approach for the halide-free, continuous-flow preparation of hydrophobic ionic liquids (ILs) relying on the bis(trifluoromethanesulfonyl)imide (bistriflimide, NTf2–) anion. The simple yet fast two-step synthetic route, which involves the formation of… read more here.
Keywords: halide free; free continuous; ionic liquids; hydrophobic ionic ... See more keywords
Feasibility and Advantages of Continuous Synthesis of Bioinspired Silica Using CO2 as an Acidifying Agent
Sign Up to like & getrecommendations! Published in 2024 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.4c03101
Abstract: In this work, we present a method for the continuous synthesis of bioinspired porous silica (BIS) particles using carbon dioxide (CO2) as an acidifying agent. Typical BIS synthesis uses strong mineral acids (e.g., HCl) to… read more here.
Keywords: co2 acidifying; continuous synthesis; acidifying agent; bis ... See more keywords
Continuous synthesis of high-entropy alloy nanoparticles by in-flight alloying of elemental metals
Sign Up to like & getrecommendations! Published in 2024 at "Nature Communications"
DOI: 10.1038/s41467-024-45731-z
Abstract: High-entropy alloy (HEA) nanoparticles (NPs) exhibit unusual combinations of functional properties. However, their scalable synthesis remains a significant challenge requiring extreme fabrication conditions. Metal salts are often employed as precursors because of their low decomposition… read more here.
Keywords: hea nps; continuous synthesis; entropy alloy; synthesis ... See more keywords
Continuous synthesis of tuneable sized silver nanoparticles via a tandem seed-mediated method in coiled flow inverter reactors
Sign Up to like & getrecommendations! Published in 2018 at "Reaction Chemistry and Engineering"
DOI: 10.1039/c7re00194k
Abstract: Size control of metal nanoparticles is essential to achieve accurate adjustment of their unique chemical and physical properties. In this work, we present a novel approach for the continuous synthesis of silver nanoparticles with tuneable… read more here.
Keywords: seed; silver nanoparticles; coiled flow; continuous synthesis ... See more keywords
Continuous synthesis of aligned carbon nanotube arrays on copper substrates using laser-activated gas jet
Sign Up to like & getrecommendations! Published in 2018 at "Applied Physics Letters"
DOI: 10.1063/1.5052283
Abstract: A method has been developed for continuous synthesis of carbon nanotube (CNT) arrays on large-area metal substrates using a reactor that moves above the substrate surface with a given scan rate. The reagent vapors pass… read more here.
Keywords: continuous synthesis; carbon nanotube; synthesis; substrates using ... See more keywords