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Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c06768
Abstract: We report here a mechanistically distinct tactic to carry E2-type eliminations on alkyl halides. This strategy exploits the interplay of α-aminoalkyl radical-mediated halogen-atom transfer (XAT) with desaturative cobalt catalysis. The methodology is high-yielding, tolerates many…
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Keywords:
alkyl halides;
atom transfer;
contra thermodynamic;
transfer xat ... See more keywords
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Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra04177d
Abstract: Halolactonization of alkenoic acids enables the construction of oxygen-heterocycles via intramolecular halonium-induced nucleophilic addition. Although the literature is currently inundated with halolactonizations of 5-aryl-4(E)-pentenoic acids that predictably afford the 6-endo cyclization adducts, methods that reliably…
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Keywords:
aryl pentenoic;
halolactonization lactam;
contra thermodynamic;
thermodynamic halolactonization ... See more keywords