Ligand-based control of nuclearity in (NHC)gold(I) sulfides.
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DOI: 10.1039/d1dt02616j
Abstract: N-Heterocyclic carbene (NHC) ligands support gold(I) sulfide complexes of varying nuclearity and charge. For sterically undemanding ligands, gold(I) chlorides react with sulfide to form trigold μ3-sulfido cations as the first observed products. The ligand IMes… read more here.
Keywords: ligand based; cation; control nuclearity; ylidene ... See more keywords